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Dipotassium cyclooctatetraenide
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Dipotassium cyclooctatetraenide : ウィキペディア英語版
Dipotassium cyclooctatetraenide

Dipotassium cyclooctatetraenide, sometimes abbreviated K2COT, is an organopotassium compound with the formula K2C8H8. It is a brown solid that is used as a precursor to cyclooctatetraenide complexes, such as uranocene (U(C8H8)2). Analogs of K2C8H8 are known with ring substituents, with different alkali metals, and with various complexants.
==Preparation and structure==
Potassium cyclooctatetraenide is formed by the reaction of cyclooctatetraene with potassium metal:
:2 K + C8H8 → K2C8H8
The reaction entails 2-electron reduction of the polyene and is accompanied by a color change from colorless to brown.
The structure of K2(diglyme)C8H8 has been characterized by X-ray crystallography of the derivatives with diglyme complexed to the potassium cations. The C8H8 unit is planar with an average C-C distance of 1.40 A.

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